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http://ciateq.repositorioinstitucional.mx/jspui/handle/1020/273| Molecular interactions arising in polyethylene-bentonite nanocomposites | |
| A. E. Bonilla-Blancas Issis Romero_Ibarra Jorge Vazquez-Arenas Octavio Manero Jose Alvarez-Ramirez | |
| En Embargo | |
| 31-10-2019 | |
| Atribución-NoComercial-CompartirIgual | |
| https://doi.org/10.1002/app.46920 1097-4628 https://onlinelibrary.wiley.com/doi/abs/10.1002/app.46920 | |
| Bentonite Functionalized ternary blends Molecular interactions Nanocomposite Polyethylene | |
| High density polyethylene (HDPE), linear low density polyethylene (LLDPE) and low density polyethylene (LDPE) are blended, and compared against a similar mixture but functionalized LDPE with maleic anhydride (MAh), HDPE‐LLDPE‐LDPE‐g‐MAh. In order to obtain nanocomposites from these polymer blends, a modified bentonite was added by incorporating l‐lysine into the bentonite galleries by melt extrusion. The resulting nanocomposites presented improved mechanical properties linked to strong polymer‐bentonite interactions and exfoliated structures as verified by transmission electron microscopy and rheometry. A detailed analysis of the feasible polymer‐bentonite interactions was conducted, of particular concern between the polar MAh groups and the intercalated l‐lysine. To gain further insights into the type of molecular interactions (i.e. polymer‐bentonite), a model nanocomposite was synthesized in solution to carry out further assessments through NMR, infrared spectroscopy and rheology analysis. Elizabeth Bonilla acknowledges the CONACYT support (PhD Scholarship, 202749). We also thank the financial support of the project PAPIIT IN 103207 from UNAM and SECITI 071/2016. Also to F. Calderas, G. Cedillo, M. Carreón for the rheological, NMR and FTIR measurements, respectively. Antonio Sánchez Solís, coautor Additional Supporting Information: https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fapp.46920&file=app46920-sup-0001-supinfo.pdf | |
| John Wiley & Sons, Inc. | |
| 2018 | |
| Artículo | |
| Journal of Applied Polymer Science, vol. 135, 46920 (9 pág.) | |
| Inglés | |
| Bonilla‐Blancas A. E., Romero‐Ibarra I. C., Vazquez‐Arenas J., Sanchez‐Solis A., Manero O. and Alvarez‐Ramirez J.. (2018), Molecular interactions arising in polyethylene‐bentonite nanocomposites. J. Appl. Polym. Sci. 46920 doi: https://doi.org/10.1002/app.46920 | |
| PRODUCTOS DERIVADOS DEL PETRÓLEO | |
| Versión aceptada | |
| acceptedVersion - Versión aceptada | |
| Aparece en las colecciones: | Artículos Publicados en Revistas Arbitradas |