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Chemically modified nanoparticles for enhanced antioxidant and antimicrobial properties with cinnamon essential oil
Aaron Azael Lopez Cano
VERONICA MARTINEZ AGUILAR
Mariana Peña-Juárez
Ricardo López Esparza
Enrique Delgado Alvarado
Emmanuel Gutierrez
MAYRA DEL ANGEL MONROY
Elias Perez
Agustin L. Herrera-May
JOSE AMIR GONZALEZ CALDERON
Acceso Abierto
Atribución-NoComercial-CompartirIgual
https://doi.org/10.3390/antiox12122057
2076-3921
https://www.mdpi.com/journal/antioxidants
https://www.mdpi.com/2076-3921/12/12/2057
Cinnamon essential oil
Antioxidant activity
Antimicrobial properties
Nanoparticles
Polylactic acid films
We explored the potential of different nanoparticles (TiO2, CaCO3, and Al2O3), considering their pure form and modified with cinnamon essential oil (CEO). These materials were characterized using various techniques, including FTIR spectroscopy, XRD analysis, TGA, and SEM. The interaction between CEO and nanoparticles changed depending on the nanoparticle type. Al2O3 nanoparticles exhibited the strongest interaction with CEO, increasing their antioxidant capacity by around 40% and their transfer of antimicrobial properties, particularly against Gram-negative bacteria. In contrast, TiO2 and CaCO3 nanoparticles showed limited interaction with CEO, resulting in lower antioxidant capacity and antimicrobial activity. Incorporating pure and CEO-modified nanoparticles into polylactic acid (PLA) films improved their mechanical and thermal properties, which are suitable for applications requiring greater strength. This research highlights the potential of metal oxide nanoparticles to enhance the antimicrobial and antioxidant capabilities of polymers. In addition, incorporating cinnamon essential oil can increase the antioxidant and antimicrobial effectiveness of the metal oxide nanoparticles and improve the mechanical and thermal properties of PLA films. Thus, these PLA films exhibit favorable characteristics for active packaging applications.
Author contributions: conceptualization, V.M.-A. and J.A.G.-C.; formal analysis, A.A.L.-C., V.M.-A., M.G.P.-J. and M.D.A.-M.; funding acquisition, A.L.H.-M.; methodology, A.A.L.-C. and V.M.-A.; investigation, E.P.; supervision, R.L.-E., E.D.-A., and E.J.G.-C.; validation, A.L.H.-M. and J.A.G.-C.; writing—original draft, V.M.-A.; writing—review and editing, M.G.P.-J. and J.A.G.-C. All authors have read and agreed to the published version of the manuscript.
Funding: J.A. Gonzalez-Calderon thanks CONAHCYT for supporting the Catedras-CONAHCYT Program, and Verónica Martinez thanks CONAHCYT for the Doctoral Fellowship. The authors also want to thank CONAHCYT for funding the project CF2019 265239 “Ciencia de Frontera”, which made this work possible.
Institutional review board statement: Not applicable.
Informed consent statement: Not applicable.
Data availability statement: Data is contained within the article.
Acknowledgments: The authors acknowledge Claudia Hernández and Rosa Lina Tovar for their support during the XRD and SEM analyses.
Conflicts of interest: The authors declare no conflict of interest.
Disclaimer/publisher’s note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.
MDPI
2023
Artículo
Antioxidants, vol. 12, no. 12, 2057
Inglés
Público en general
López-Cano, A.A.; Martínez-Aguilar, V.; Peña-Juárez, M.G.; López-Esparza, R.; Delgado-Alvarado, E.; Gutiérrez-Castañeda, E.J.; Del Angel-Monroy, M.; Pérez, E.; Herrera-May, A.L.; Gonzalez-Calderon, J.A. Chemically Modified Nanoparticles for Enhanced Antioxidant and Antimicrobial Properties with Cinnamon Essential Oil. Antioxidants 2023, 12, 2057. https://doi.org/10.3390/antiox12122057
OTRAS
Versión publicada
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